Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of Cyclotrimethylenetrinitramine (RDX) in Binary Solvent Mixtures

Kim, D. J.[Dong Joo], Kim, K. -J.[Kwang-Joo]
J. Chem. Eng. Data 2007, 52, 5, 1946-1949
ABSTRACT
Experimental solubilities of cyclotrimethylenetrinitramine (RDX) in binary solvent mixtures, such as c-butyrolactone + water, cyclohexanone + water, N-methyl pyrrolidone + water, and acetone + water, were measured over the temperature range of 273.15 K to 363.15 K. The enthalpy of dissolution was determined experimentally from the solubility data.
Compounds
# Formula Name
1 C3H6N6O6 1,3,5-triaza-1,3,5-trinitrocyclohexane
2 C4H6O2 .gamma.-butyrolactone
3 C5H9NO N-methylpyrrolidone
4 C6H10O cyclohexanone
5 C3H6O acetone
6 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • 6
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Solvent: Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Addition of solute until saturation
  • 20
  • POMD
  • 4
  • 1
  • 6
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Solvent: Mass fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Addition of solute until saturation
  • 20
  • POMD
  • 1
  • 3
  • 6
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Solvent: Mass fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Addition of solute until saturation
  • 20
  • POMD
  • 5
  • 1
  • 6
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Solvent: Mass fraction - 5; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Addition of solute until saturation
  • 20