Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Quantitative Determination of Binodal and Phase Equilibrium Diagrams for the Ternary System (Fluorobenzene + Water + 2-Propanol) at Three Temperatures

Atik, Z.[Zadjia], Chaou, M.[Malika]
J. Chem. Eng. Data 2007, 52, 5, 2056-2058
ABSTRACT
This work reports new experimental data on the solubilities and liquid-liquid phase diagrams of the ternary system water + 2-propanol + fluorobenzene at temperatures of (288.15, 298.15, and 308.15) K and a pressure of 101.2 kPa. The experimental data were correlated quantitatively by means of the nonrandom two liquid (NRTL) and universal quasi chemical (UNIQUAC) thermodynamic models and were consistent to better than 0.3 % in the phase composition. The effect of temperature on the miscibility of the ternary systems is generally small.
Compounds
# Formula Name
1 H2O water
2 C3H8O propan-2-ol
3 C6H5F fluorobenzene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 3
  • 1
  • Mole fraction - 2 ; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 61
  • POMD
  • 2
  • 3
  • 1
  • Mole fraction - 2 ; Liquid mixture 1
  • Mole fraction - 2 ; Liquid mixture 2
  • Mole fraction - 1 ; Liquid mixture 2
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • Chromatography
  • Chromatography
  • 20