Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Thermodynamic Properties of Inorganic Salts in Nonaqeous Solvents. IV. Apparent Molar Volumes and Compressibilities of Divalent Transition-Metal Bromides and Chlorides in Acetonitrile

Krakowiak, J.[Joanna], Warminska, D.[Dorota], Grzybkowski, W.[Waclaw]
J. Chem. Eng. Data 2007, 52, 6, 2105-2109
ABSTRACT
The densities of divalent transition-metal bromides and chlorides in acetonitrile at (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, and 323.15) K and sound velocities at 298.15 K have been measured. From these data, apparent molar volumes V1/4 at (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, and 323.15) K and the apparent molar isentropic compressibility KS,1/4 at T ) 298.15 K of transition-metal bromides and chloride in acetonitrile have been determined.
Compounds
# Formula Name
1 Br2Mn manganese(II) bromide
2 Br2Co cobalt(II) bromide
3 Br2Zn zinc bromide
4 Cl2Co cobalt chloride
5 Cl2Zn zinc chloride
6 C2H3N acetonitrile
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 6
  • Speed of sound, m/s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Pulse-echo method
  • 1
  • POMD
  • 6
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 35
  • POMD
  • 6
  • 1
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Pulse-echo method
  • 6
  • POMD
  • 6
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 98
  • POMD
  • 6
  • 2
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Pulse-echo method
  • 8
  • POMD
  • 6
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 98
  • POMD
  • 6
  • 3
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 3; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Pulse-echo method
  • 7
  • POMD
  • 6
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 91
  • POMD
  • 6
  • 4
  • Speed of sound, m/s ; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Pulse-echo method
  • 8
  • POMD
  • 6
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 63
  • POMD
  • 6
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 5; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • VIBTUB:UFactor:4
  • 77