The molar enthalpies of solution of ionic liquid (IL) [C6mim][Cl] (l-hexyl-3-methylimidazolium chloride) at various molalities in water were measured by a solution-reaction isoperibol calorimeter at 298.15 K. According to Pitzer's electrolyte solution theory, the molar standard enthalpy of solution of [C6mim][Cl], jj.sotlfJ ill and Pitzer's parameters, f3(O)LMX' f3MX(I)L, and C'PL MX' were obtained. In terms of the experimental data in literature, the mean contribution per methylene (-CH2-) group to the standard molar enthalpies of solution of [Cxmim][Cl] is discussed.
Compounds
#
Formula
Name
1
H2O
water
2
C10H19ClN2
1-hexyl-3-methylimidazolium chloride
3
C4H11NO3
2-amino-2-(hydroxymethyl)-1,3-propanediol
4
ClH
hydrogen chloride
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.