Precise density and sound velocity measurements have been carried out on tripotassium citrate in aqueous solutions of polypropylene oxide (PPO) 400 over a range of temperatures at atmospheric pressure. The data obtained are used to calculate the apparent molar volume and isentropic compressibility as a function of temperature and concentration. Apparent molar volume and isentropic compressibility values have been fitted to a Redlich- Mayer-type equation from which the apparent molar volume and apparent molar isentropic compressibility of the solutions at infinite dilution have also been calculated at each temperature. The results show a positive transfer volume of tripotassium citrate from pure water to an aqueous PPO solution. The apparent molar isentropic compressibility of tripotassium citrate in aqueous PPO solutions is negative which implies that the water molecules around the tripotassium citrate are less compressible than the water molecules in the bulk solutions.
Compounds
#
Formula
Name
1
H2O
water
2
C6H5K3O7
potassium citrate
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.