ABSTRACT

Liquid-liquid equilibrium data have been determined experimentally for {1-methyl-3-octylimidazolium tetrafluoroborate + thiophene + hexane} and {1-methyl-3-octylimidazolium tetrafluoroborate + thiophene + cyclohexane} ternary systems at 298.15 K. The compositions of the ends of the tie-lines were obtained by gas chromatographic analysis of phases at equilibrium. Data have been adequately correlated using the nonrandom two-liquid (NRTL) activity coefficient model despite this being an equation intended for nonelectrolyte solutions.

Compounds

#	Formula	Name
1	C6H14	hexane
2	C6H12	cyclohexane
3	C12H23BF4N2	1-methyl-3-octylimidazolium tetrafluoroborate
4	C4H4S	thiophene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	4 1 3	Mole fraction - 1 ; Liquid mixture 1 Mole fraction - 1 ; Liquid mixture 2 Mole fraction - 4 ; Liquid mixture 2	Mole fraction - 4; Liquid mixture 1	Temperature, K; Liquid mixture 1 Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Chromatography Chromatography Chromatography	13
POMD	4 2 3	Mole fraction - 4 ; Liquid mixture 2 Mole fraction - 3 ; Liquid mixture 1 Mole fraction - 4 ; Liquid mixture 1	Mole fraction - 3; Liquid mixture 2	Temperature, K; Liquid mixture 1 Pressure, kPa; Liquid mixture 1	Liquid mixture 2 Liquid mixture 1	Chromatography Chromatography Chromatography	11

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Liquid-Liquid Equilibria for Systems Composed by 1-Methyl-3-octylimidazolium Tetrafluoroborate Ionic Liquid, Thiophene, and n-Hexane or Cyclohexane

Alonso, L.[Lusia], Arce, A.[Alberto], Francisco, M.[Maria], Rodriguez, O.[Oscar], Soto, A.[Ana]

ABSTRACT