Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement of CO2 Solubility in NaCl Brine Solutions at Different Temperatures and Pressures Using the Potentiometric Titration Method

Mohammadian, E.[Erfan], Hamidi, H.[Hossein], Assadullah, M.[Mohammad], Azdarpour, A.[Amin], Motamedi, S.[Shervin], Junin, R.[Radzuan]
J. Chem. Eng. Data 2015, 60, 7, 2042-2049
ABSTRACT
The solubility of CO2 in brine is one of the trapping mechanisms by which the CO2 is sequestrated in aquifers. In this research, an unconventional method, called the potentiometric titration, was used to obtain the solubility of CO2 in distilled water and NaCl brine. The solubility data for the low salinity range are scarce in the literature. Thus, in this research, the CO2 solubility was obtained in NaCl brines of low salinity (0 15?000 ppm) at temperatures between 60 deg C and 100 deg C and pressures up to 25 MPa. Moreover, the salting-out effect was estimated using the Setchenov s constant as a measure of reduction in solubility when salt is added to the solution. The solubility points obtained by the potentiometric titration method demonstrated very good consistency with those obtained by the previous methods.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 H2O water
3 ClNa sodium chloride
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Molality, mol/kg - 1 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • potentiometric titration
  • 20
  • POMD
  • 1
  • 3
  • 2
  • Molality, mol/kg - 1 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Solvent: Molality, mol/kg - 3; Liquid
  • Liquid
  • Gas
  • potentiometric titration
  • 49