Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Volumetric Properties of Disaccharides in Aqueous Solutions of Benzyldimethylammonium Acetate as a Function of Temperature

Singh, V.[Vickramjeet], Banipal, P. K.[Parampaul K.], Banipal, T. S.[Tarlok S.], Gardas, R. L.[Ramesh L.]
J. Chem. Eng. Data 2015, 60, 6, 1764-1775
ABSTRACT
Densities, ?, and speeds of sound, u, of two disaccharides (D-(+)-maltose and D-(+)-cellobiose) in water and in the presence of protic ionic liquid (PIL) (i.e., benzyldimethylammonium acetate, BDMAAc) were measured at different temperatures (288.15 318.15) K at atmospheric pressure. These data were used to calculate the apparent molar volume, apparent molar isentropic compressibility, infinite dilution partial molar volume, infinite dilution partial molar isentropic compressibility, and corresponding transfer parameters (?tVdeg 2 and ?tKdeg s,2) for disaccharides from water to aqueous PIL solutions. The effect of BDMAAc on the basic taste quality of disaccharides was evaluated from apparent specific volume and apparent specific isentropic compressibility, as these parameters are grouped in various taste qualities.
Compounds
# Formula Name
1 C12H22O11 D-cellobiose
2 H2O water
3 C11H17NO2 N,N-dimethylbenzylammonium acetate
4 C12H24O12 D-(+)-maltose monohydrate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Solvent: Molality, mol/kg - 3; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 140
  • POMD
  • 1
  • 2
  • 3
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Solvent: Molality, mol/kg - 3; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • LVPAI:UFactor:3
  • 140
  • POMD
  • 4
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Solvent: Molality, mol/kg - 3; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 120
  • POMD
  • 4
  • 2
  • 3
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Solvent: Molality, mol/kg - 3; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • LVPAI:UFactor:2
  • 120
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 24
  • POMD
  • 1
  • 2
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • LVPAI:UFactor:3
  • 24
  • POMD
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 16
  • POMD
  • 2
  • 3
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 3; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • LVPAI:UFactor:3
  • 16
  • POMD
  • 4
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 24
  • POMD
  • 4
  • 2
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Frequency, MHz; Liquid
  • Liquid
  • LVPAI:UFactor:2
  • 24