Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Isothermal Vapor Liquid Equilibrium for the Binary System of 2,3,3,3-Tetrafluoropropene and 2-Chloro-1,1,1,2-tetrafluoropropane

Yang, Z.-q.[Zhi-qiang], Kou, L.-g.[Lian-gang], Mao, W.[Wei], Lu, J.[Jing], Zhang, W.[Wei], Lu, J.[Jian]
J. Chem. Eng. Data 2015, 60, 4, 1153-1156
ABSTRACT
The vapor liquid equilibrium (VLE) of the binary system of 2,3,3,3-tetrafluoropropene (HFO-1234yf) and 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) was measured at three temperatures from (293.15 to 313.15) K. The measurements were performed with an apparatus based on the static-analysis method. By analyzing the VLE data, the binary system shows a small deviation from the Raoult s law, and does not exhibit the azeotropic behavior over the range of investigated temperatures. In addition, the experimental VLE data were correlated with the Peng Robinson equations of state with the Huron Vidal mixing rules. Good consistency was obtained between the experimental and correlated values at each experimental isothermal.
Compounds
# Formula Name
1 C3H2F4 2,3,3,3-tetrafluoro-1-propene
2 C3H3ClF4 2-chloro-1,1,1,2-tetrafluoropropane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 3
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 3
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 30
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 30