Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solid Liquid Phase Equilibrium of Phosphoramidic acid, N,N'-1,2-Ethanediylbis-P,P,P',P'-tetraphenyl Ester in Selected Solvents

Chen, B.[Baokuan], Du, C.[Chaojun], Zhou, H.[Hui], Wang, J.[Jingjing], Wang, L.[Lijuan]
J. Chem. Eng. Data 2015, 60, 6, 1693-1698
ABSTRACT
Phosphoramidic acid, N,N'-1,2-ethanediylbis-P,P,P',P'-tetraphenyl ester (PAETE) was prepared and characterized by elemental analysis (EA), mass spectra (MS), infrared spectroscopy (IR), and nuclear magnetic resonance (NMR). The thermostability of PAETE was measured via thermogravimetric analysis (TGA). The melting temperature and the fusion enthalpy of PAETE were evaluated by differential scanning calorimeter (DSC). The solubilities of PAETE in ten selected solvents were obtained using a gravimetric method. The experimental data were well correlated by the Buchowski Ksiazczak (?h), Scatchard Hildebrand, modified Apelblat model, and the ideal equations. The solubility parameter of PAETE was estimated by the Scatchard Hildebrand Model. The dissolution enthalpy and entropy of PAETE in the ten selected solvents were also calculated by the modified Apelblat model.
Compounds
# Formula Name
1 CH4O methanol
2 C3H6O acetone
3 C4H8O tetrahydrofuran
4 C4H8O2 ethyl acetate
5 CHCl3 trichloromethane
6 C2H6O ethanol
7 C6H6 benzene
8 C3H6O2 methyl ethanoate
9 C7H8 toluene
10 C2H3N acetonitrile
11 C26H26N2O6P2 diphenyl N,N'-(ethane-1,2-diyl)bis(P-phenylphosphonamidate)
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 11
  • Normal melting temperature, K ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • DTA
  • 1
  • POMD
  • 11
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal
  • Crystal
  • Liquid
  • Air at 1 atmosphere
  • DSC
  • 1
  • POMD
  • 1
  • 11
  • Mole fraction - 11 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 11
  • Gravimetric
  • 9
  • POMD
  • 2
  • 11
  • Mole fraction - 11 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 11
  • Gravimetric
  • 8
  • POMD
  • 3
  • 11
  • Mole fraction - 11 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 11
  • Gravimetric
  • 8
  • POMD
  • 4
  • 11
  • Mole fraction - 11 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 11
  • Gravimetric
  • 11
  • POMD
  • 5
  • 11
  • Mole fraction - 11 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 11
  • Gravimetric
  • 8
  • POMD
  • 6
  • 11
  • Mole fraction - 11 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 11
  • Gravimetric
  • 11
  • POMD
  • 7
  • 11
  • Mole fraction - 11 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 11
  • Gravimetric
  • 11
  • POMD
  • 8
  • 11
  • Mole fraction - 11 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 11
  • Gravimetric
  • 8
  • POMD
  • 9
  • 11
  • Mole fraction - 11 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 11
  • Gravimetric
  • 9
  • POMD
  • 10
  • 11
  • Mole fraction - 11 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 11
  • Gravimetric
  • 9