Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

P ? T Data for 1-Butanol and Isobutyl Alcohol from (283.15 to 363.15) K at Pressures up to 66 MPa

Iglesias-Silva, G.[Gustavo], Bravo_Sachez, M.[Micael], Estrada-Baltazar, A.[Alejandro], Bouchot, C.[Christian]
J. Chem. Eng. Data 2015, 60, 4, 1076-1090
ABSTRACT
We present densities of pure 1-butanol and isobutyl alcohol from (283.15 to 363.15) K at pressures up to 66 MPa. We have measured densities using a vibrating tube densimeter. We use a forced path calibration method since this method depends mainly upon the mechanical properties of the cell. Experimental measurements of n-heptane have been measured to test the reliability of the apparatus. These measurements agree with a reference equation of state within 0.1 %. The new experimental densities of 1-butanol and isobutyl alcohol agree within 0.2 % with densities from the literature.
Compounds
# Formula Name
1 C4H10O butan-1-ol
2 C4H10O 2-methyl-1-propanol
3 C7H16 heptane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 625
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 642
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 629