Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Isothermal Vapor Liquid Equilibrium of Ethanol + Glycerol and 2-Propanol + Glycerol at Different Temperatures

Wibawa, G.[Gede], Mustain, A.[Asalil], Akbarina, M. F.[Masita F.], Ruslim, R. M.[Rika M.]
J. Chem. Eng. Data 2015, 60, 3, 955-959
ABSTRACT
Isothermal vapor liquid equilibrium (VLE) data for two binary mixtures of ethanol + glycerol and 2-propanol + glycerol were determined at the temperature range from (323.15 to 343.15) K using a simple quasistatic ebulliometer. The experimental data were correlated with the Wilson, nonrandom two-liquid (NRTL), and universal quasichemical (UNIQUAC) activity coefficient models. Both systems show that the vapor pressures increase with increasing alcohols concentrations, and no azeotropic behaviors are exhibited. In addition, both systems show positive deviations from the Raoult s Law.
Compounds
# Formula Name
1 C2H6O ethanol
2 C3H8O propan-2-ol
3 C3H8O3 glycerol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 3
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 20
  • POMD
  • 3
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 20