Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Viscosities of Fatty Acid Methyl and Ethyl Esters under High Pressure: Methyl Caprate and Ethyl Caprate

Habrioux, M.[Matthieu], Bazile, J.-P.[Jean-Patrick], Galliero, G.[Guillaume], Daridon, J. L.[Jean Luc]
J. Chem. Eng. Data 2015, 60, 3, 902-908
ABSTRACT
The paper reports high pressure data of the viscosity of methyl caprate (C11H22O2) and ethyl caprate (C12H24O2). The measurements cover the temperature range from (293.15 to 353.15) K, from atmospheric pressure up to 200 MPa and were carried out by two different methods. One is based on a falling-body viscometer, whereas the other rests on a quartz crystal resonator technique. Based on the two sets of data, high pressure viscosity correlations are proposed to correlate within the experimental uncertainty the viscosity values as a function of temperature and pressure. Finally, a thermodynamic scaling method was used to describe the viscosity in terms of density and temperature.
Compounds
# Formula Name
1 C11H22O2 methyl decanoate
2 C12H24O2 ethyl decanoate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 42
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Quartz crystal resonator
  • 44
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Quartz crystal resonator
  • 18
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 44
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Quartz crystal resonator
  • 44
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Quartz crystal resonator
  • 20