The solubilities of tetraphenyl piperazine-1,4-diyldiphosphonate (TPPDP) in (dichloromethane + ethanol) and (dichloromethane + n-hexane) were measured at temperatures from (283.15 to 308.15) K using a static analytic method. Experimental data are well-represented by the modified Apelblat and (CNIBS)/Redlich Kister equations for describing the effects of temperature and solvent composition on solubility, respectively. It was found that TPPDP solubility in dichloromethane + n-hexane decreases with the addition of n-hexane, whereas it shows a maximum in dichloromethane + ethanol. The solubility data are well-correlated by Wilson, NRTL, and Jouyban Acree models, in which Jouyban Acree model achieves the best fitting results. Based on the modified Apelblat equation, the thermodynamic properties (i.e., the Gibbs free energy, enthalpy, and entropy) of solution in two binary solvent mixtures were derived. The results indicate that the dissolution of TPPDP in all studied cases is not spontaneous and energetic predominance.
Compounds
#
Formula
Name
1
C28H28N2O6P2
tetraphenyl piperazine-1,4-diylbis(phosphonate)
2
C2H6O
ethanol
3
CH2Cl2
dichloromethane
4
C6H14
hexane
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.