Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of Dimethyl Ether in Pentaerythritol Tetrahexanoate (PEC6) and in Pentaerythritol Tetraoctanoate (PEC8) Between (283.15 and 353.15) K

SUN, Y.[Yanjun], Wang, X.[Xiaopo], Gong, N.[Na], Liu, Z.[Zhigang]
J. Chem. Eng. Data 2014, 59, 11, 3791-3797
ABSTRACT
The solubilities of dimethyl ether (DME) in pentaerythritol tetrahexanoate (PEC6) and in pentaerythritol tetraoctanoate (PEC8) have been measured from (283.15 to 353.15) K based on the isochoric method. The expanded uncertainty (k = 2) of the measured solubility data was estimated to be less than 3.0 %. The experimental solubility data were correlated based on the Peng Robinson equation of state with Huron Vidal mixing rules and the NRTL equation for the excess Gibbs energy at infinite pressure. The absolute average deviation between experimental data and calculated values was 1.1 % and 1.0 % for DME + PEC6 system and DME + PEC8 system, respectively. The maximum absolute deviation was 2.93 % for the DME + PEC6 system and 2.90 % for DME + PEC8 system.
Compounds
# Formula Name
1 C2H6O dimethyl ether
2 C29H52O8 pentaerythritol tetrahexanoate
3 C37H68O8 pentaerythritol tetraoctanoate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • pressure drop
  • 64
  • POMD
  • 1
  • 3
  • Mole fraction - 1 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • pressure drop
  • 64