ABSTRACT

The density, viscosity, and refractive index of binary mixtures consisting of ethyl-butyrate + 1-propanol, 2-methyl-1-propanol, 1-butanol, 3-methyl-1-butanol, or 1-hexanol have been measured at atmospheric pressure and over the temperature range from (288.15 to 323.15) K. Excess and deviation functions have been calculated from these data and fitted to the Redlich Kister equation. The values of excess molar volume and deviation functions were further used in the analysis of molecular interactions present in the mixture as well as the temperature influence on them.

Compounds

#	Formula	Name
1	C6H12O2	ethyl butanoate
2	C3H8O	propan-1-ol
3	C4H10O	2-methyl-1-propanol
4	C4H10O	butan-1-ol
5	C5H12O	3-methylbutan-1-ol
6	C6H14O	hexan-1-ol

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	8
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	9
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	8
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	8
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	8
POMD	3	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	8
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	8
POMD	4	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	8
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	8
POMD	5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	8
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	8
POMD	6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	8
POMD	2 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	88
POMD	2 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	88
POMD	3 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	88
POMD	3 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	88
POMD	4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	88
POMD	4 1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	88
POMD	1 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	88
POMD	1 5	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	88
POMD	1 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	88
POMD	1 6	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Falling or rolling sphere viscometry	88

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Volumetric and Viscometric Study of Binary Systems of Ethyl Butyrate with Alcohols

Bajic, D.[Divna], Zivkovic, E.[Emila], Serbanovic, S.[Slobodan], Kijevcanin, M.[Mirjana]

ABSTRACT