Name: ThermoML Representation of Published Experimental Data from Journal of Chemical and Engineering Data (0021-9568, American Chemical Society)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Oxygenated Compounds + Hydrocarbon Mixtures in Fuels and Biofuels: Excess Enthalpies of Ternary Mixtures Containing 1-Butoxybutane + Propan-1-ol +1-Hex-1-ene, or Heptane, or 2,2,4-Trimethylpentane at (298.15 and 313.15) K

Alaoui, F. E. M.[Fatima E.M.], Aguilar, F.[Fernando], Gonzalez-Fernandez, M. J.[Maria Jesus], Amarti, A. E.[Ahmed El], Montero, E. A.[Eduardo A.]

J. Chem. Eng. Data 2014, 59, 9, 2856-2864

ABSTRACT

New experimental excess molar enthalpy data (376 points) of the ternary systems 1-butoxybutane + propan-1-ol +1-hex-1-ene, or heptane, or 2,2,4-trimethylpentane and the corresponding binary systems at (298.15 and 313.15) K at atmospheric pressure are reported. A quasi-isothermal flow calorimeter has been used to make the measurements. All of the binary and ternary systems show endothermic character at both temperatures. The experimental data for the binary systems have been fitted using the rational equations

Compounds

#	Formula	Name
1	C3H8O	propan-1-ol
2	C8H18O	dibutyl ether
3	C6H12	hex-1-ene
4	C7H16	heptane
5	C8H18	2,2,4-trimethylpentane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 2	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	38
POMD	1 3	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	38
POMD	1 4	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	38
POMD	1 5	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	38
POMD	1 2 3	Molar enthalpy of mixing with solvent, kJ/mol - 3 ; Liquid	Temperature, K; Liquid Solvent: Amount ratio of component to other component of binary solvent - 2; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	87
POMD	1 4 2	Molar enthalpy of mixing with solvent, kJ/mol - 4 ; Liquid	Temperature, K; Liquid Solvent: Amount ratio of component to other component of binary solvent - 2; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	88
POMD	1 2 5	Molar enthalpy of mixing with solvent, kJ/mol - 5 ; Liquid	Temperature, K; Liquid Solvent: Amount ratio of component to other component of binary solvent - 2; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	88