Experimental measurements of the liquid liquid equilibrium of the ternary system consisting of acetone + solketal + glycerol were made. The conditions selected for this study were (303.2, 313.2, and 323.2) K at 101.3 kPa, relevant for the synthesis of solketal from glycerol and acetone through a ketalization reaction. The data obtained were correlated to the nonrandom two liquid (NRTL) model, and the binary interaction parameters of the ternary system were retrieved after the optimization of the nonrandomness binary interaction parameters. The liquid liquid equilibrium data predicted by the NRTL model agreed adequately with the experimental results.
Compounds
#
Formula
Name
1
C3H8O3
glycerol
2
C6H12O3
2,2-dimethyl-1,3-dioxolane-4-methanol
3
C3H6O
acetone
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.