ABSTRACT

The measurements of the liquid liquid coexistence curve and the heat capacity for binary mixture {1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([C2mim][NTf2]) + 1-propanol} have been precisely performed. The values of the critical exponents a and ss in the critical region were obtained and coincided well with the 3D-Ising ones. The complete scaling theory was applied to well represent the asymmetric behavior of the diameter of the coexistence curve, indicating an important role of the heat capacity related term in the complete scaling formulizm. A comparison of the reduced critical parameters to those predicted by the restricted primitive model clearly showed the solvophobic criticality of the studied system.

Compounds

#	Formula	Name
1	C8H11F6N3O4S2	1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide
2	C3H8O	propan-1-ol

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (other wavelength) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid Wavelength, nm; Liquid	Liquid	Standard Abbe refractometry	10
POMD	2	Refractive index (other wavelength) ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid Wavelength, nm; Liquid	Liquid	Standard Abbe refractometry	9
POMD	2 1	Mole fraction - 1 ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Index of refraction calibration data	30
POMD	2 1	Mole fraction - 1 ; Liquid mixture 2	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 2 Liquid mixture 1	Index of refraction calibration data	30
POMD	2 1	Refractive index (other wavelength) ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid Wavelength, nm; Liquid	Liquid	Standard Abbe refractometry	14
POMD	2 1	Heat capacity at constant pressure per volume, J/K/m3 ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Differential Scanning Calorimeter	3
POMD	2 1	Heat capacity at constant pressure per volume, J/K/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid Mole fraction - 1; Liquid	Liquid	Differential Scanning Calorimeter	37

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Liquid Liquid Phase Equilibrium and Heat Capacity of Binary Mixture 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide + 1-Propanol

Wang, M.[Mingjie], Yin, T.[Tianxiang], Xu, C.[Chen], Chen, Z.[Zhiyun], Shen, W.[Weiguo]

ABSTRACT