Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Determination and Correlation of Solubilities of Lauric Acid in Eight Alcohols

Yang, Z.-H.[Zhi-Hong], Zeng, Z.-X.[Zuo-Xiang], Sun, L.[Li], Xue, W.-L.[Wei-Lan], Chen, N.[Nan]
J. Chem. Eng. Data 2014, 59, 9, 2725-2731
ABSTRACT
The solubilities of lauric acid in methanol, ethanol, propanol, n-butanol, n-pentanol, n-hexanol, isobutanol, and isoamylol were measured by synthetic method in the temperature ranging from (276.17 to 306.12) K. Results of these measurements were correlated by the modified Apelblat equation, the ?h equation and activity coefficient models (NRTL and UNIQUAC). It was found that the modified Apelblat equation and the ?h equation gave better correlation results. The thermodynamic properties of the solution process, including the Gibbs energy, enthalpy, and entropy were calculated by the van t Hoff analysis.
Compounds
# Formula Name
1 C12H24O2 dodecanoic acid
2 CH4O methanol
3 C2H6O ethanol
4 C3H8O propan-1-ol
5 C4H10O butan-1-ol
6 C5H12O pentan-1-ol
7 C6H14O hexan-1-ol
8 C4H10O 2-methyl-1-propanol
9 C5H12O 3-methylbutan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • laser beam
  • 11
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • laser beam
  • 11
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • laser beam
  • 11
  • POMD
  • 5
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • laser beam
  • 11
  • POMD
  • 6
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • laser beam
  • 11
  • POMD
  • 7
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • laser beam
  • 11
  • POMD
  • 8
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • laser beam
  • 11
  • POMD
  • 9
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • laser beam
  • 11