ABSTRACT

Standard partial molar volumes, V2o, at infinite dilution and viscosity B-coefficients (employing the Jones Dole equation) have been calculated from the respective density and efflux time measurements for various solutes (mono-, di-, and trisaccharides, and their derivatives; methyl glycosides) in aqueous solutions of lithium chloride of (0.5, 1.0, 2.0, and 3.0) mol*kg 1 at temperatures of (288.15 to 318.15) K. The corresponding transfer parameters, interaction coefficients, partial molar expansibilities, and dB/dT coefficients have been evaluated and discussed in terms of the solute solvent and solute cosolute interactions. The results have been compared for the solutes studied in the presence of (1:1 and 1:2/2:1) electrolytes to arrive at the conclusions of how these solutes interact with the mono- and divalent cations.

Compounds

#	Formula	Name
1	C5H10O5	D-xylose
2	C5H10O5	D-(-)-arabinose
3	C5H10O5	D-ribose
4	C6H12O6	D-glucose
5	C6H12O6	D-mannose
6	C6H12O6	(+)-galactose
7	C6H12O6	D-fructose
8	C12H22O11	6-.alpha.-D-galactopyranosyl-D-glucopyranose
9	C12H22O11	D-cellobiose
10	C12H22O11	D-sucrose
11	C12H24O12	D-(+)-maltose monohydrate
12	C12H24O12	4-O-.beta.-D-galactopyranosyl-D-glucose hydrate (1:1)
13	C12H26O13	D-(+)-trehalose dihydrate
14	C18H42O21	D-raffinose, pentahydrate
15	C7H14O6	methyl-.alpha.-D-glucopyranoside
16	C6H12O5	methyl .alpha.-D-xylopyranoside
17	C6H12O5	methyl .beta.-D-xylopyranoside
18	ClLi	lithium chloride
19	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	112
POMD	1 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	112
POMD	18 19 2	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 2; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	96
POMD	18 19 2	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 2; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	3 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 3; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	96
POMD	3 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 3; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	4 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	96
POMD	4 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	5 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 5; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	96
POMD	5 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 5; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	6 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 6; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	96
POMD	6 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 6; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	7 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 7; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	96
POMD	7 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 7; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	8 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 8; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	96
POMD	8 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 8; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	9 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 9; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	96
POMD	9 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 9; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	10 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 10; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	96
POMD	10 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 10; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	11 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 11; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	96
POMD	11 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 11; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	18 19 12	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 12; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	96
POMD	18 19 12	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 12; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	13 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 13; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	96
POMD	13 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 13; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	18 19 14	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 14; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	96
POMD	18 19 14	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 14; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	96
POMD	15 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 15; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	80
POMD	15 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 15; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	80
POMD	16 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 16; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	84
POMD	16 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 16; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	84
POMD	17 18 19	Mass density, kg/m3 ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 17; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	80
POMD	17 18 19	Viscosity, Pa*s ; Liquid	Solvent: Molality, mol/kg - 18; Liquid Temperature, K; Liquid Molality, mol/kg - 17; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	80
POMD	18 19	Mass density, kg/m3 ; Liquid	Molality, mol/kg - 18; Liquid Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:12	16
POMD	18 19	Viscosity, Pa*s ; Liquid	Molality, mol/kg - 18; Liquid Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	16

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Studies on the Interactions of Saccharides and Methyl Glycosides with Lithium Chloride in Aqueous Solutions at (288.15 to 318.15) K

Banipal, P. K.[Parampaul K.], Hundal, A.[Amanpreet], Aggarwal, N.[Neha], Banipal, T.[Tarlok]

ABSTRACT