Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor Pressures and Vaporization Enthalpies of a Series of Dialkyl Phthalates by Correlation Gas Chromatography

Gobble, C.[Chase], Chickos, J.[James], Verevkin, S. P.[Sergey P.]
J. Chem. Eng. Data 2014, 59, 4, 1353-1365
ABSTRACT
Experimental vapor pressures, vaporization, fusion and sublimation enthalpies of a number of dialkyl benzenedicarboxylates have been examined by correlation gas chromatography (CGC) experiments in order to identify a series of experimental measurements that appear to be internally self-consistent. The compounds studied in this regard include dimethyl phthalate dimethyl terephthalate, dimethyl isophthalate, diethyl phthalate, dibutyl phthalate, and bis(2-ethylhexyl) phthalate. New vaporization enthalpies and liquid vapor pressure equations (T/K = 298.15 to 550) of several other compounds are reported also evaluated by CGC experiments. The compounds, the vaporization, fusion, and sublimation enthalpies and liquid and solid vapor pressures evaluated are summarized in Table 22 of the text.
Compounds
# Formula Name
1 C10H10O4 dimethyl 1,4-benzenedicarboxylate
2 C16H22O4 dibutyl phthalate
3 C19H20O4 benzyl butyl 1,2-benzenedioate
4 C20H26O4 dicyclohexyl phthalate
5 C24H38O4 bis(2-ethylhexyl) terephthalate
6 C24H38O4 dioctyl 1,2-benzenedicarboxylate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Metastable liquid
  • Temperature, K; Metastable liquid
  • Metastable liquid
  • Gas
  • Gas chromatography
  • 1
  • POMD
  • 2
  • Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Correlation gas chromatography
  • 1
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Transpiration method
  • 10
  • POMD
  • 3
  • Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Correlation gas chromatography
  • 1
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Gas chromatography
  • 1
  • POMD
  • 4
  • Molar enthalpy of transition or fusion, kJ/mol ; Crystal
  • Crystal
  • Liquid
  • Gas
  • DSC
  • 1
  • POMD
  • 4
  • Triple point temperature, K ; Crystal
  • Crystal
  • Liquid
  • Gas
  • DTA
  • 1
  • POMD
  • 4
  • Molar enthalpy of vaporization or sublimation, kJ/mol ; Metastable liquid
  • Temperature, K; Metastable liquid
  • Metastable liquid
  • Gas
  • Correlation gas chromatography
  • 1
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Metastable liquid
  • Temperature, K; Metastable liquid
  • Metastable liquid
  • Gas
  • Gas chromatography
  • 1
  • POMD
  • 5
  • Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Correlation gas chromatography
  • 1
  • POMD
  • 5
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Gas chromatography
  • 1
  • POMD
  • 6
  • Molar enthalpy of vaporization or sublimation, kJ/mol ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Correlation gas chromatography
  • 1
  • POMD
  • 6
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Gas chromatography
  • 1