Name: ThermoML Representation of Published Experimental Data from Journal of Chemical and Engineering Data (0021-9568, American Chemical Society)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Experimental Measurements and Correlations of Excess Molar Enthalpies for the Binary and Ternary Mixtures of (Cyclohexane, 1,4-Dioxane and Piperidine) or (Cyclohexane, Morpholine and Piperidine) at 308.15 K and Atmospheric Pressure

Belaribi, F. B.[Farid Brahim], Boukais-Belaribi, G.[Ghenima], Dahmoun, A.[Atika], Dahmani, A.[Aomar], Mohammadi, A. H.[Amir H.], Richon, D.[Dominique]

J. Chem. Eng. Data 2014, 59, 5, 1629-1635

ABSTRACT

Excess molar enthalpies for the binary and ternary mixtures of (cyclohexane, 1,4-dioxane, and piperidine) and (cyclohexane, morpholine, and piperidine) were measured using a Calvet microcalorimeter at 308.15 K and atmospheric pressure. The empirical equations of Redlich Kister and Cibulka were used to correlate the experimental excess molar enthalpies for the binary and ternary mixtures, respectively. The capability of artificial neural network algorithm to model these data is also studied.

Compounds

#	Formula	Name
1	C6H12	cyclohexane
2	C5H11N	piperidine
3	C4H9NO	tetrahydro-1,4-oxazine
4	C4H8O2	1,4-dioxane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	2 3	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 3; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Calvet calorimetry	9
POMD	1 2 3	Molar enthalpy of mixing with solvent, kJ/mol - 2 ; Liquid	Solvent: Amount ratio of component to other component of binary solvent - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Calvet calorimetry	17
POMD	1 2 4	Molar enthalpy of mixing with solvent, kJ/mol - 2 ; Liquid	Solvent: Amount ratio of component to other component of binary solvent - 1; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Calvet calorimetry	23
POMD	2 4	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 4; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Calvet calorimetry	9