Name: ThermoML Representation of Published Experimental Data from Journal of Chemical and Engineering Data (0021-9568, American Chemical Society)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Measurement of Vapor Liquid Equilibria for the Binary Mixture of Octafluoropropane and Hexafluoropropylene Oxide Containing Octafluorocyclobutane

Kim, Y. L.[Young Lae], Park, S. J.[Sung Jin], Choi, H.[HoYun], Baek, J.-m.[Jong-min], Song, H. D.[Han Dock], Jung, S. J.[Sung Jin], Lee, K. J.[Kun Jong]

J. Chem. Eng. Data 2014, 59, 7, 2164-2170

ABSTRACT

Isothermal vapor liquid equilibrium (VLE) data were measured for the binary systems of octafluoropropane + octafluorocyclobutane and hexafluoropropylene oxide + octafluorocyclobutane system at the temperature range from 263.15 K to 303.15 K. The experiments were carried out with a circulating-type equilibrium apparatus including online gas chromatography analysis. The VLE data were correlated well by the Peng Robinson equation of state using the Wong Sandler mixing rules involving the NRTL model. All the binary parameters of these systems and the average absolute deviations (AADs) in terms of saturated pressure and vapor phase composition between the experimental and calculated values are represented.

Compounds

#	Formula	Name
1	C3F8	octafluoropropane
2	C4F8	octafluorocyclobutane
3	C3F6O	2,2,3-trifluoro-3-(trifluoromethyl)oxirane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	5
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	5
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	5
POMD	1 2	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 1; Liquid Temperature, K; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	58
POMD	1 2	Mole fraction - 1 ; Gas	Mole fraction - 1; Liquid Temperature, K; Liquid	Gas Liquid	Chromatography	58
POMD	2 3	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 3; Liquid Temperature, K; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	42
POMD	2 3	Mole fraction - 3 ; Gas	Mole fraction - 3; Liquid Temperature, K; Liquid	Gas Liquid	Chromatography	42