Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Liquid Liquid Equilibria for the Ternary Systems of 4-Methyl-1,3-dioxolan-2-one + 1,4-Dimethylbenzene + Octane, Decane, or Dodecane and the Ternary Systems of Acetonitrile + Morpholine + Octane, Decane, or Dodecane at 313.15 K or 298.15 K

Lee, T. G.[Tae Gyu], Lim, S. Y.[Sang Young], Song, K. H.[Kwang Ho], Choe, J.[Jaehoon]
J. Chem. Eng. Data 2014, 59, 3, 890-895
ABSTRACT
The phase behavior of a temperature-dependent multicomponent system was investigated for ternary systems comprising a polar aprotic solvent, a solubility mediator, and aliphatic hydrocarbons such as octane, decane, or dodecane. The experimental tie-line composition and binodal composition were obtained for the ternary system of 4-methyl-1,3-dioxolan-2-one + 1,4-dimethylbenzene + octane, decane, or dodecane and the ternary system of acetonitrile + morpholine + octane, decane, or dodecane at two different temperatures, 298.15 K and 313.15 K. The distribution ratios of 1,4-dimethylbenzene and morpholine were determined, and the experimental tie-line results were adequately correlated using the nonrandom two-liquid (NRTL) activity coefficient model by utilizing the obtained binary interaction parameter.
Compounds
# Formula Name
1 C4H6O3 4-methyl-1,3-dioxolan-2-one
2 C8H10 1,4-dimethylbenzene
3 C8H18 octane
4 C10H22 decane
5 C12H26 dodecane
6 C2H3N acetonitrile
7 C4H9NO tetrahydro-1,4-oxazine
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • 3
  • Mole fraction - 2 ; Liquid mixture 2
  • Mole fraction - 1 ; Liquid mixture 1
  • Mole fraction - 2 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • Chromatography
  • Chromatography
  • 16
  • POMD
  • 2
  • 1
  • 3
  • Mole fraction - 2 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 17
  • POMD
  • 6
  • 7
  • 3
  • Mole fraction - 6 ; Liquid mixture 2
  • Mole fraction - 6 ; Liquid mixture 1
  • Mole fraction - 7 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 7; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • Chromatography
  • Chromatography
  • 16
  • POMD
  • 6
  • 7
  • 3
  • Mole fraction - 7 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 6; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 11
  • POMD
  • 2
  • 1
  • 4
  • Mole fraction - 2 ; Liquid mixture 2
  • Mole fraction - 1 ; Liquid mixture 1
  • Mole fraction - 2 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • Chromatography
  • Chromatography
  • 16
  • POMD
  • 2
  • 1
  • 4
  • Mole fraction - 2 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 19
  • POMD
  • 2
  • 1
  • 5
  • Mole fraction - 2 ; Liquid mixture 2
  • Mole fraction - 1 ; Liquid mixture 1
  • Mole fraction - 2 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • Chromatography
  • Chromatography
  • 16
  • POMD
  • 2
  • 1
  • 5
  • Mole fraction - 2 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 17
  • POMD
  • 6
  • 7
  • 4
  • Mole fraction - 6 ; Liquid mixture 2
  • Mole fraction - 6 ; Liquid mixture 1
  • Mole fraction - 7 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 7; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • Chromatography
  • Chromatography
  • 16
  • POMD
  • 6
  • 7
  • 4
  • Mole fraction - 7 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 6; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 14
  • POMD
  • 6
  • 7
  • 5
  • Mole fraction - 6 ; Liquid mixture 2
  • Mole fraction - 6 ; Liquid mixture 1
  • Mole fraction - 7 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 7; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • Chromatography
  • Chromatography
  • 16
  • POMD
  • 6
  • 7
  • 5
  • Mole fraction - 7 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Mole fraction - 6; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 16