Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of 1-Fluoro-4-(methylsulfonyl)benzene in Five Pure Organic Solvents at Temperatures from (288.40 to 331.50) K

Qian, C.[Chao], Wang, Y.[Yayun], Chen, X.[Xinzhi]
J. Chem. Eng. Data 2014, 59, 4, 1254-1256
ABSTRACT
The solubilities of 1-fluoro-4-(methylsulfonyl)benzene in five pure organic solvents (ethanol, ethyl acetate, acetone, toluene, and chloroform) at temperatures ranging from (288.40 to 331.50) K under atmospheric pressure were measured experimentally by the dynamic method with a laser monitoring apparatus. It was found that the solubilities in different solvents decreased in the order chloroform greater than acetone greater than ethyl acetate greater than toluene greater than ethanol. The experimental data were well-correlated using the modified Apelblat equation, with average relative deviations of less than 2.92 % and root-mean-square deviations of no more than 0.30 %.
Compounds
# Formula Name
1 C7H7FO2S 1-fluoro-4-(methylsulfonyl)benzene
2 CHCl3 trichloromethane
3 C3H6O acetone
4 C7H8 toluene
5 C4H8O2 ethyl acetate
6 C2H6O ethanol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 7
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 6
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 7
  • POMD
  • 5
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 7
  • POMD
  • 6
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Titration method
  • 7