Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Density, Viscosity, Speed of Sound, Bulk Modulus, Surface Tension, and Flash Point of Direct Sugar to Hydrocarbon Diesel (DSH-76) and Binary Mixtures of N-Hexadecane and 2,2,4,6,6-Pentamethylheptane

Prak, D. J. L.[Dianne J. Luning], Morris, R. E.[Robert E.], Cowart, J. S.[Jim S.], Hamilton, L. J.[Leonard J.], Trulove, P. C.[Paul C.]
J. Chem. Eng. Data 2013, 58, 12, 3536-3544
ABSTRACT
The physical properties of direct sugar to hydrocarbon diesel (DSH-76) and several binary mixtures of n-hexadecane and 2,2,4,6,6-pentamethylheptane were measured in this work. The density and viscosity were measured at temperatures ranging from (293.15 to 393.15) K, and the pure component values fell within the range of previously reported values. Speed of sound data at temperatures ranging from (293.15 to 323.15) K increased from (1089 to 1357) m*s 1. The bulk modulus was calculated from the density and speed of sound data, and its values ranged from (858 to 1425) MPa. Flash point values ranged from (318 to 408) K, and the surface tension values ranged from (21.8 to 27.3) mN*m 1. The values of density, viscosity, speed of sound, bulk modulus, flash point (378 K), and surface tension (25.0 mN*m 1) for the DSH-76 fell within the range of values measured for the binary mixtures of n-hexadecane and 2,2,4,6,6-pentamethylheptane. These data suggest that a binary mixture of n-hexadecane and 2,2,4,6,6-pentamethylheptane may be a suitable surrogate for renewable fuels such as DSH-76.
Compounds
# Formula Name
1 C16H34 hexadecane
2 C12H26 2,2,4,6,6-pentamethylheptane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 9
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Concentric cylinders viscometry
  • 9
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 9
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Concentric cylinders viscometry
  • 9
  • POMD
  • 2
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pulse-echo method
  • 4
  • POMD
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Pendant drop shape
  • 1
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 72
  • POMD
  • 1
  • 2
  • Viscosity, Pa*s ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Concentric cylinders viscometry
  • 72
  • POMD
  • 1
  • 2
  • Speed of sound, m/s ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pulse-echo method
  • 28
  • POMD
  • 1
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Pendant drop shape
  • 7