Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Physicochemical Properties of Aqueous Solutions of Sodium l-Prolinate as an Absorbent for CO2 Removal

Shaikh, M. S., Shariff, A. M., Bustam, M. A., Murshid, G.[Ghulam]
J. Chem. Eng. Data 2014, 59, 2, 362-368
ABSTRACT
The physicochemical properties such as density, viscosity, and refractive index of aqueous solutions of sodium l-prolinate (SP) as a solvent for CO2 capture was measured. These properties were measured at different temperatures from (298.15 to 343.15) K. The mass fractions of SP were 0.05, 0.10, 0.20, 0.30, and 0.40. The coefficient of thermal expansion was calculated from the experimental density values in the same temperature range. The analysis of experimental results shows that the densities, viscosities, and refractive indices of the aqueous solutions of SP increase with an increase in the mass fraction in the solution, and decrease with increasing temperature. The thermal expansion coefficient slightly increases with increasing temperature and concentration. The experimental data of density, viscosity, and refractive index were correlated by the least-squares method as a function of temperature. The predicted data were estimated from correlation coefficients for all measured properties and reported with standard deviations.
Compounds
# Formula Name
1 C5H8NNaO2 sodium L-prolinate
2 C2H7NO 2-aminoethan-1-ol
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 5
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 5
  • POMD
  • 2
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 5
  • POMD
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 50
  • POMD
  • 3
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • SPHERE:UFactor:2
  • 50
  • POMD
  • 3
  • 1
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 50