Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor Liquid Equilibrium (VLE) Data and Thermodynamic Modeling for Binary Systems Containing Perfluorobutane (R610) with Carbon Monoxide or Nitric Oxide at (293, 313, and 333) K

Tshibangu, M. M.[Mulamba M.], Valtz, A.[Alain], Narasigadu, C.[Caleb], Coquelet, C.[Christophe], Ramjugernath, D.[Deresh]
J. Chem. Eng. Data 2014, 59, 2, 346-354
ABSTRACT
Isothermal vapor liquid equilibrium data are presented for binary systems containing perfluorobutane with carbon monoxide or nitric oxide. The measurements were undertaken for both systems at three temperatures ranging from (293 to 333) K, with pressures ranging from (0.965 to 16.130) MPa. The measured data were successfully correlated via the direct method using the Peng Robinson equation of state incorporating the Mathias Copeman/Stryjek Vera alpha function and the Wong Sandler mixing rule utilizing the nonrandom two-liquid (NRTL) activity coefficient model.
Compounds
# Formula Name
1 C4F10 decafluorobutane
2 CO carbon monoxide
3 NO nitrogen oxide (NO)
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 39
  • POMD
  • 1
  • 2
  • Mole fraction - 2 ; Gas
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 39
  • POMD
  • 1
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 33
  • POMD
  • 1
  • 3
  • Mole fraction - 3 ; Gas
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 33