ABSTRACT

Knowledge of accurate vapor liquid equilibrium data for mixtures of allyl chloride and 1,5-hexadiene is important for several industrial purposes. The bubble points of binary mixtures of allyl chloride and 1,5-hexadiene have been measured experimentally using a synthetic method. Measurements were carried over concentrations ranging from (0 to 1) mol % of allyl chloride. The vapor liquid equilibrium is presented at temperatures ranging from (25 to 100) deg C. Within this temperature range, bubble-point pressures up to 5 bar were observed. The experimental results indicated that, as the concentration of allyl chloride increases in the mixture, higher pressures are necessary for a complete dissolution of the two components. In addition, solubility pressures increase as temperature increases for a mixture of fixed composition.

Compounds

#	Formula	Name
1	C6H10	1,5-hexadiene
2	C3H5Cl	3-chloro-1-propene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Closed cell (Static) method	7
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Closed cell (Static) method	13
POMD	2 1	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 1; Liquid Temperature, K; Liquid	Liquid Gas	Closed cell (Static) method	54

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Vapor Liquid Equilibria of the Binary System 1,5-Hexadiene + Allyl Chloride

Raeissi, S.[Sona], Florusse, L. J.[Louw J.], Peters, C. J.[Cor J.]

ABSTRACT