Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Liquid Liquid Equilibria for the System Water + 1,3-Dichloro-2-propanol + Epichlorohydrin from (283.2 to 303.2) K

Wang, R.[Rui], Lu, Y.[Yangcheng], Wang, K.[Kai], Luo, G.[Guangsheng]
J. Chem. Eng. Data 2013, 58, 11, 3222-3225
ABSTRACT
Liquid liquid equilibrium data for the ternary system of water + 1,3-dichloro-2-propanol + epichlorohydrin were determined at the temperature of (283.15, 293.15, 303.15) K and atmosphere pressure. The reliability of experimental method was examined by the mass balance verification and the Othmer Tobias equation. The experimental data were successfully correlated with both the NRTL model and UNIQUAC model, and the NRTL model presents more satisfactory result. These LLE data and model parameters obtained in this work are helpful for understanding, designing, and developing epichlorohydrin synthesis processes.
Compounds
# Formula Name
1 C3H6Cl2O 1,3-dichloro-2-propanol
2 C3H5ClO 1-chloro-2,3-epoxypropane
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 3 ; Liquid mixture 1
  • Mass fraction - 3 ; Liquid mixture 2
  • Mass fraction - 1 ; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Mass fraction - 1; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • Chromatography
  • Chromatography
  • 30
  • POMD
  • 2
  • 3
  • Mass fraction - 3 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 3
  • POMD
  • 2
  • 3
  • Mass fraction - 3 ; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • 3
  • POMD
  • 1
  • 3
  • Mass fraction - 3 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 3
  • POMD
  • 1
  • 3
  • Mass fraction - 3 ; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • 3