Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Volumetric Properties of Binary Mixtures of 3-(Methylamino)propylamine with Water, N-Methyldiethanolamine, N,N-Dimethylethanolamine, and N,N-Diethylethanolamine from (283.15 to 363.15) K

Wang, X.[Xiaopo], Kang, K.[Kai], Wang, W.[Wei], Tian, Y.[Yuansi]
J. Chem. Eng. Data 2013, 58, 12, 3430-3439
ABSTRACT
Experimental density data of the binary mixtures of 3-(methylamino)propylamine with water, N-methyldiethanolamine, N,N-dimethylethanolamine and N,N-diethylethanolamine were reported at atmospheric pressure over the entire composition range at temperatures from (283.15 to 363.15) K. The densities were measured using an Anton Paar digital vibrating U-tube densimeter. Excess molar volumes of the mixture were calculated from the experimental densities and correlated as the Redlich Kister equation. The optimized sets of parameters of the equation were obtained by the least-squares method at each temperature. Infinite dilution partial molar volumes and the corresponding excess partial molar volumes at infinite dilution were calculated and discussed. Thermal expansivities for the binary mixtures were presented.
Compounds
# Formula Name
1 C4H12N2 N-methyl-1,3-diaminopropane
2 C5H13NO2 N-methyldiethanolamine
3 C4H11NO 2-(N,N-dimethylamino)ethanol
4 C6H15NO (diethylamino)ethanol
5 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 9
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 8
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 9
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 9
  • POMD
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 9
  • POMD
  • 1
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 153
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 88
  • POMD
  • 4
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 99
  • POMD
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 99