Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Heat Capacities of Four Promising Alternatives to Lithium Bromide Aqueous Solution in Absorption Refrigerators

Gao, N.[Neng], Chen, G.[Guangming], Jiang, Y.[Yunyun], Fang, L.[Lingyun], He, Y.[Yijian]
J. Chem. Eng. Data 2013, 58, 11, 3155-3159
ABSTRACT
Properly choosing additives to conventional lithium bromide aqueous solution to improve the performance is an important part in lithium bromide absorption refrigeration studies. Mixtures consisting of lithium bromide + triethylene glycol + water, lithium bromide + propylene glycol + water, lithium bromide + sodium formate + water, and lithium bromide + potassium formate + water were thought to be four promising alternatives to lithium bromide aqueous solutions. In the study, heat capacities of the four kinds of solutions were measured using a calvet type calorimeter at temperatures from 308.15 K to 348.15 K. The experimental data were regressed using a stepwise statistical method, and the corresponding equations for each kind of solution were given. The average absolute deviations between experimental and calculated values were no more than 0.12 % for all of the systems.
Compounds
# Formula Name
1 BrLi lithium bromide
2 CHNaO2 sodium methanoate
3 CHKO2 potassium formate
4 C3H8O2 1,2-propanediol
5 C6H14O4 triethylene glycol
6 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 5
  • 1
  • 6
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Mass fraction - 5; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • LDSC:UFactor:0.5
  • 40
  • POMD
  • 4
  • 1
  • 6
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Mass fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • LDSC:UFactor:0.5
  • 40
  • POMD
  • 2
  • 1
  • 6
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • LDSC:UFactor:0.5
  • 40
  • POMD
  • 3
  • 1
  • 6
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Mass fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • LDSC:UFactor:0.5
  • 30