Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubility of 3,4-Bis(3-nitrofurazan-4-yl)furoxan in Common Solvents at Temperatures between 293.15 K and 313.15 K

Cui, K.[Kejian], Xu, Z.-b.[Zhi-bin], Chen, L.[Liru], Xue, M.[Min], Meng, Z.-h.[Zi-hui], Xu, G.[Guangrui], Wang, R.[Rui], Liu, W.[Wenjin], Lin, Z.[Zhihui]
J. Chem. Eng. Data 2013, 58, 9, 2677-2680
ABSTRACT
The solubility of 3,4-bis(3-nitrofurazan-4-yl)furoxan (DNTF) was measured in water, dichloromethane, ethanol, ethyl ethanoate, methanol, and trichloromethane between 293.15 K and 313.15 K. Measurements were performed by using high-pressure liquid chromatography with ultraviolet detection. For all reagents tested, the solubility of DNTF increased as temperature increased. The solubility data were correlated with temperature as an exponential function. The enthalpy of solution in each solvent was calculated by an analysis of temperature dependence.
Compounds
# Formula Name
1 C6N8O8 3,4-bis(3-nitrofurazan-4-yl)furoxan
2 CH2Cl2 dichloromethane
3 C2H6O ethanol
4 C4H8O2 ethyl acetate
5 CH4O methanol
6 CHCl3 trichloromethane
7 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 7
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 5
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 5
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 5
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 5
  • POMD
  • 5
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 5
  • POMD
  • 6
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 5