ABSTRACT

A fluorous biphasic system consists of a fluorinated solvent and an organic solvent. The mutual solubility data of fluorous biphasic systems were analyzed for common organic solvents such as benzene, toluene, and xylene with perfluamine. Fluorous/organic amphiphilic ether solvents such as HFE7300 and HFE7500 were added to the fluorous biphasic system. The equilibrium tie lines for ternary systems were determined at two different temperatures, and the equilibrium data sets were correlated with the nonrandom two-liquid and universal quasichemical models.

Compounds

#	Formula	Name
1	C9F21N	1,1,2,2,3,3,3-heptafluoro-N,N-bis(heptafluoropropyl)-1-propanamine
2	C7H3F13O	1,1,1,2,2,3,3,5,5,5-decafluoro-4-methoxy-4-(trifluoromethyl)pentane
3	C9H5F15O	2-trifluoromethyl-3-ethoxydodecafluorohexane
4	C6H6	benzene
5	C7H8	toluene
6	C8H10	1,2-dimethylbenzene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	4 1 2	Mass fraction - 1 ; Liquid mixture 1 Mass fraction - 1 ; Liquid mixture 2 Mass fraction - 2 ; Liquid mixture 2	Temperature, K; Liquid mixture 2 Mass fraction - 2; Liquid mixture 1	Pressure, kPa; Liquid mixture 2	Liquid mixture 1 Liquid mixture 2	Chromatography Chromatography Chromatography	16
POMD	5 1 2	Mass fraction - 2 ; Liquid mixture 2 Mass fraction - 1 ; Liquid mixture 1 Mass fraction - 2 ; Liquid mixture 1	Temperature, K; Liquid mixture 1 Mass fraction - 1; Liquid mixture 2	Pressure, kPa; Liquid mixture 1	Liquid mixture 2 Liquid mixture 1	Chromatography Chromatography Chromatography	16
POMD	6 1 2	Mass fraction - 1 ; Liquid mixture 1 Mass fraction - 2 ; Liquid mixture 2 Mass fraction - 1 ; Liquid mixture 2	Temperature, K; Liquid mixture 2 Mass fraction - 2; Liquid mixture 1	Pressure, kPa; Liquid mixture 2	Liquid mixture 1 Liquid mixture 2	Chromatography Chromatography Chromatography	16
POMD	4 1 3	Mass fraction - 3 ; Liquid mixture 2 Mass fraction - 1 ; Liquid mixture 1 Mass fraction - 3 ; Liquid mixture 1	Temperature, K; Liquid mixture 1 Mass fraction - 1; Liquid mixture 2	Pressure, kPa; Liquid mixture 1	Liquid mixture 2 Liquid mixture 1	Chromatography Chromatography Chromatography	16
POMD	5 1 3	Mass fraction - 3 ; Liquid mixture 2 Mass fraction - 1 ; Liquid mixture 1 Mass fraction - 3 ; Liquid mixture 1	Temperature, K; Liquid mixture 1 Mass fraction - 1; Liquid mixture 2	Pressure, kPa; Liquid mixture 1	Liquid mixture 2 Liquid mixture 1	Chromatography Chromatography Chromatography	16
POMD	6 1 3	Mass fraction - 3 ; Liquid mixture 2 Mass fraction - 1 ; Liquid mixture 1 Mass fraction - 3 ; Liquid mixture 1	Temperature, K; Liquid mixture 1 Mass fraction - 1; Liquid mixture 2	Pressure, kPa; Liquid mixture 1	Liquid mixture 2 Liquid mixture 1	Chromatography Chromatography Chromatography	16

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Liquid Liquid Equilibria for the Ternary Systems of Perfluamine + Hydrofluoroether + Benzene, Toluene, or Xylene at 298.15 K or 313.15 K

Lee, T. G.[Tae Gyu], Song, K. H.[Kwang Ho], Choe, J.[Jaehoon]

ABSTRACT