Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Speed of Sound, Density, and Derivative Properties of Methyl Oleate and Methyl Linoleate under High Pressure

Ndiaye, E. H. I.[El Hadji I.], Habrioux, M.[Matthieu], Coutinho, J. A. P.[Joao A. P.], Paredes, M. L. L.[Marcio L. L.], Daridon, J. L.[Jean Luc]
J. Chem. Eng. Data 2013, 58, 8, 2345-2354
ABSTRACT
Speeds of sound were measured for methyl oleate and methyl linoleate (C15H30O2) at pressures up to 200 MPa along isotherms ranging from (283.15 to 393.15) K. Additional density measurements were carried out by using a U-tube densimeter up to 100 MPa from (293 to 393) K. From the integration of speed of sound, density was evaluated up to 200 MPa, and the isentropic compressibility was determined in the same p T domain. A correlation that represents both the density and the speed of sound within their experimental uncertainties is reported to evaluate both the volume and its derivatives with respect to pressure (isothermal compressibility) and temperature (isobaric expansion).
Compounds
# Formula Name
1 C19H36O2 methyl cis-9-octadecenoate
2 C19H34O2 methyl (Z,Z)-9,12-octadecadienate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Speed of sound, m/s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Pulse-echo method
  • 147
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Vibrating tube method
  • 121
  • POMD
  • 2
  • Speed of sound, m/s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Pulse-echo method
  • 130
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Vibrating tube method
  • 121