ABSTRACT

The densities, ?, and viscosities, ?, of some mono-, di-, and trisaccharides in (0.05, 0.10, 0.12, and 0.15) mol*kg 1 aqueous disodium tetraborate (borax) solutions have been determined at (288.15 to 318.15) K, by using a vibrating-tube digital densimeter and an Ubbelohde-type capillary viscometer, respectively. From these data, the standard partial molar volumes at infinite dilution, V2deg and Jones-Dole viscosity B coefficients have also been evaluated. Their significantly large positive values vary with the size of saccharides, i.e., from mono- to di- to trisaccharides. The results have been discussed in terms of the solute cosolute interactions occurring in these solutions.

Compounds

#	Formula	Name
1	C5H10O5	D-xylose
2	C5H10O5	D-(-)-arabinose
3	C5H10O5	D-ribose
4	C6H12O6	L-sorbose
5	C6H12O6	D-fructose
6	C6H12O6	(+)-galactose
7	C6H12O6	D-glucose
8	C6H12O6	D-mannose
9	C12H22O11	D-cellobiose
10	C12H22O11	D-sucrose
11	C12H22O11	6-.alpha.-D-galactopyranosyl-D-glucopyranose
12	C12H24O12	4-O-.beta.-D-galactopyranosyl-D-glucose hydrate (1:1)
13	C12H24O12	D-(+)-maltose monohydrate
14	C18H32O16	O-.alpha.-glucopyranosyl-(1,3)-O-.beta.-D- fructofuranosyl-(2,1)-.alpha.-D-glucopyranoside
15	C12H26O13	D-(+)-trehalose dihydrate
16	C18H42O21	D-raffinose, pentahydrate
17	B4Na2O7	sodium tetraborate
18	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 17 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	84
POMD	1 17 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	84
POMD	17 18 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 2; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	56
POMD	17 18 2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 2; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	56
POMD	3 17 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 3; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	32
POMD	3 17 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 3; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	56
POMD	4 17 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	60
POMD	4 17 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 4; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	84
POMD	5 17 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 5; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	84
POMD	5 17 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 5; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	72
POMD	6 17 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 6; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	84
POMD	6 17 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 6; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	84
POMD	7 17 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 7; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	84
POMD	7 17 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 7; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	84
POMD	9 17 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 9; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	70
POMD	9 17 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 9; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	56
POMD	10 17 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 10; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	84
POMD	10 17 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 10; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	84
POMD	11 17 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 11; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	70
POMD	11 17 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 11; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	70
POMD	17 18 12	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 12; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	104
POMD	17 18 12	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 12; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	84
POMD	17 15 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 15; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	70
POMD	17 15 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 15; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	66
POMD	17 13 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 13; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	84
POMD	17 13 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 13; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	84
POMD	14 17 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 14; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	56
POMD	14 17 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 14; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	56
POMD	17 18 16	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 16; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	70
POMD	17 18 16	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 16; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	56
POMD	17 8 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 8; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	84
POMD	17 8 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Solvent: Molality, mol/kg - 17; Liquid Molality, mol/kg - 8; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	84
POMD	17 18	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Molality, mol/kg - 17; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	14
POMD	17 18	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 17; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	14

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Volumetric and Viscometric Studies on Saccharide-Disodium Tetraborate (Borax) Interactions in Aqueous Solutions

Banipal, P. K.[Parampaul K.], Singh, V.[Vickramjeet], Banipal, T. S.[Tarlok S.]

ABSTRACT