Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Experimental Measurements of Vapor Liquid Equilibrium Data for the Binary Systems of Methanol + 2-Butyl Acetate, 2-Butyl Alcohol + 2-Butyl Acetate, and Methyl Acetate + 2-Butyl Acetate at 101.33 kPa

Wang, H.-x.[Hong-xing], Xiao, J.-j.[Jing-jing], Shen, Y.-y.[Yan-yi], Ye, C.-s.[Chang-shen], Li, L.[Ling], Qiu, T.[Ting]
J. Chem. Eng. Data 2013, 58, 6, 1827-1832
ABSTRACT
The isobaric vapor liquid equilibrium measurements for the systems of 2-butyl acetate with three chemicals (methanol, 2-butyl alcohol, methyl acetate) were determined respectively in a modified Rose still at 101.33 kPa. Thermodynamic consistency of the three binary vapor liquid equilibrium data had been confirmed by Herington methods. The three groups of experimental data were all correlated with NRTL and Wilson models, respectively. The binary interaction parameters of both models had been obtained by the simplex method. The NRTL and Wilson equations showed low deviation with respect to the experimental data.
Compounds
# Formula Name
1 CH4O methanol
2 C4H10O butan-2-ol
3 C3H6O2 methyl ethanoate
4 C6H12O2 1-methylpropyl ethanoate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO::UFactor:2
  • 1
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO::UFactor:2
  • 1
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO::UFactor:2
  • 1
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 1
  • POMD
  • 1
  • 4
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • CHROM:UFactor:2
  • 23
  • POMD
  • 1
  • 4
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Gas
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 23
  • POMD
  • 2
  • 4
  • Mole fraction - 2 ; Gas
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • CHROM:UFactor:2
  • 25
  • POMD
  • 2
  • 4
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Gas
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 25
  • POMD
  • 3
  • 4
  • Mole fraction - 3 ; Gas
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • CHROM:UFactor:2
  • 27
  • POMD
  • 3
  • 4
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Gas
  • Liquid
  • Gas
  • EBULLIO:UFactor:2
  • 27