ABSTRACT

Ternary LLE data have been experimentally measured for several systems consisting of biodiesel compounds. Systems measured include mixtures with the methyl esters of lauric, myristic, palmitic, and oleic acids, each with glycerin and water. Data were collected at atmospheric pressure and 60 deg C. These ternary systems have been correlated using the NRTL equation. These data and correlation parameters can be used to improve separations efficiency in transesterified biodiesel fuels.

Compounds

#	Formula	Name
1	C13H26O2	methyl dodecanoate
2	C15H30O2	methyl tetradecanoate
3	C17H34O2	methyl hexadecanoate
4	C19H36O2	methyl cis-9-octadecenoate
5	C3H8O3	glycerol
6	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	5 1 6	Mole fraction - 1 ; Liquid mixture 2 Mole fraction - 5 ; Liquid mixture 1 Mole fraction - 6 ; Liquid mixture 1	Mole fraction - 6; Liquid mixture 2	Temperature, K; Liquid mixture 1 Pressure, kPa; Liquid mixture 1	Liquid mixture 2 Liquid mixture 1	Chromatography Chromatography Chromatography	8
POMD	5 2 6	Mole fraction - 2 ; Liquid mixture 2 Mole fraction - 5 ; Liquid mixture 1 Mole fraction - 6 ; Liquid mixture 1	Mole fraction - 6; Liquid mixture 2	Temperature, K; Liquid mixture 1 Pressure, kPa; Liquid mixture 1	Liquid mixture 2 Liquid mixture 1	Chromatography Chromatography Chromatography	8
POMD	5 3 6	Mole fraction - 5 ; Liquid mixture 1 Mole fraction - 3 ; Liquid mixture 2 Mole fraction - 6 ; Liquid mixture 2	Mole fraction - 6; Liquid mixture 1	Temperature, K; Liquid mixture 2 Pressure, kPa; Liquid mixture 2	Liquid mixture 1 Liquid mixture 2	Chromatography Chromatography Chromatography	7
POMD	5 4 6	Mole fraction - 5 ; Liquid mixture 1 Mole fraction - 4 ; Liquid mixture 2 Mole fraction - 6 ; Liquid mixture 2	Mole fraction - 6; Liquid mixture 1	Temperature, K; Liquid mixture 2 Pressure, kPa; Liquid mixture 2	Liquid mixture 1 Liquid mixture 2	Chromatography Chromatography Chromatography	8

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Article Ternary Liquid Liquid Equilibrium of Biodiesel Compounds for Systems Consisting of a Methyl Ester + Glycerin + Water

Bell, J.[Joseph], Messerly, R.[Richard], Gee, R.[Ryan], Harrison, A.[Aaron], Rowley, R. L.[Richard L.], Wilding, W. V.[W. Vincent]

ABSTRACT