ABSTRACT

The results of the density measurements for the pair systems containing nitromethane with 1,1,2,2-tetrachloroethane, 1,1,1-trichloroethane, chloroform, 1,2-dichloroethane, 1,3-dichloropropane, 1,4-dichlorobutane, 1-chlorobutane, and 1-chloropentane at T = (298.15, 308.15, and 318.15) K and atmospheric pressure on entire compositional range are reported. The derived excess molar volumes, VE, are positive for the nitromethane + 1,1,1-trichloroethane, + 1,2-dichloroethane, + 1,3-dichloropropane, + 1,4-dichlorobutane, + 1-chlorobutane, and + 1-chloropentane binary mixtures, and they are negative for the other two systems: nitromethane + 1,1,2,2-tetrachloroethane, and + chloroform, on the entire compositional range and at all three studied temperatures. The excess molar volumes have been correlated with the three-parameter Redlich Kister equation.

Compounds

#	Formula	Name
1	CH3NO2	nitromethane
2	C2H2Cl4	1,1,2,2-tetrachloroethane
3	C2H3Cl3	1,1,1-trichloroethane
4	CHCl3	trichloromethane
5	C2H4Cl2	1,2-dichloroethane
6	C3H6Cl2	1,3-dichloropropane
7	C4H8Cl2	1,4-dichlorobutane
8	C4H9Cl	1-chlorobutane
9	C5H11Cl	1-chloropentane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	17
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	8	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	9	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	3
POMD	1 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	3 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	1 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	1 6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	1 7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	1 8	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 8; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	1 9	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 9; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33
POMD	4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	33

Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Volumetric Study for the Binary Nitromethane with Chloroalkane Mixtures at Temperatures in the Range (298.15 to 318.15) K

Gheorghe, D.[Daniela], Dragoescu, D.[Dana], Teodorescu, M.[Mariana]

ABSTRACT