Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solid Liquid Equilibria of Ternary 4-Nitro-2-benzofuran-1,3-dione + 5-Nitro-2-benzofuran-1,3-dione + 2-Propanone at 283.15 K and 323.15 K

Li, R.-R.[Rong-Rong], Han, D.-M.[De-Man], Pan, F.-Y.[Fu-You], Jia, W.-P.[Wen-Ping], Jin, Y.-X.[Yan-Xian], Zhao, J.[Jia], You, Y.-J.[Yu-Jing]
J. Chem. Eng. Data 2013, 58, 3, 682-685
ABSTRACT
In this work, solid liquid equilibria (SLE) data for the ternary 4-nitro-2-benzofuran-1,3-dione + 5-nitro-2-benzofuran-1,3-dione + 2-propanone system have been measured at (283.15 and 323.15) K respectively. The solid liquid phase diagrams of the ternary system were constructed based on the measured solubility data. The Schreinemaker s wet residue method was used to confirm the solid phases formed in the system. Furthermore, the density (?) of equilibrium liquid phase was gained. At (283.15 and 323.15) K, two pure solids formed which correspond to 4-nitro-2-benzofuran-1,3-dione and 5-nitro-2-benzofuran-1,3-dione in the ternary 4-nitro-2-benzofuran-1,3-dione + 5-nitro-2-benzofuran-1,3-dione + 2-propanone system.
Compounds
# Formula Name
1 C8H3NO5 3-nitro-1,2-benzenedicarboxylic acid anhydride
2 C8H3NO5 4-nitro-1,2-benzenedicarboxylic acid anhydride
3 C3H6O acetone
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 3
  • 1
  • 2
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 9
  • POMD
  • 3
  • 1
  • 2
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Chromatography
  • 17
  • POMD
  • 3
  • 1
  • 2
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Crystal - 2
  • Chromatography
  • 2
  • POMD
  • 3
  • 1
  • 2
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Crystal - 2
  • Chromatography
  • 2
  • POMD
  • 3
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • HPLC
  • 9
  • POMD
  • 3
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • HPLC
  • 17
  • POMD
  • 3
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Crystal - 2
  • HPLC
  • 2
  • POMD
  • 3
  • 1
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Chromatography
  • 2
  • POMD
  • 3
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • HPLC
  • 2
  • POMD
  • 3
  • 2
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Chromatography
  • 2
  • POMD
  • 3
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Pycnometric method
  • 2