Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Speed of Sound and Adiabatic Compressibility of 1-Ethyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide under Pressures up to 100 MPa

Dzida, M.[Marzena], Chorazewski, M.[Miroslaw], Geppert-Rybczynska, M.[Monika], Zorebski, E.[Edward], Zorebski, M.[Michal], Zarska, M.[Monika], Czech, B.[Bozena]
J. Chem. Eng. Data 2013, 58, 6, 1571-1576
ABSTRACT
The speed of ultrasound measurements in 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, [EMIm][NTf2], were performed in the temperature range from (288 to 318) K and at pressures from (15 to 101) MPa. The speeds of ultrasound, densities, and isobaric heat capacities have been determined at ambient pressure for temperatures from (287 to 323) K, (278.15 to 363.15) K, and (293.15 to 323.15) K, respectively. The pressure dependence of densities and adiabatic compressibilities were calculated using the speeds of ultrasound at high pressure as well as densities and heat capacities at ambient pressure. The experimental densities reported in the literature are in a good agreement with the densities calculated in this work.
Compounds
# Formula Name
1 C8H11F6N3O4S2 1-ethyl-3-methylimidazolium bis((trifluoromethyl)sulfonyl)imide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pulse-echo method
  • 14
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 8
  • POMD
  • 1
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Large sample (1 g) DSC
  • 13
  • POMD
  • 1
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pulse-echo method
  • 35