Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubilities, Vapor Pressures, Densities, Viscosities, and Specific Heat Capacities of the LiNO3/H2O Binary System

Luo, C.[Chunhuan], Su, Q.[Qingquan], Mi, W.[Wanliang]
J. Chem. Eng. Data 2013, 58, 3, 625-633
ABSTRACT
The solubility, vapor pressure, density, viscosity, and specific heat capacity of LiNO3/H2O were measured in this work. The solubilities were measured in ranges of temperature from 277.15 K to 431.15 K. The vapor pressures were measured in ranges of temperature and absorbent mass fraction from 297.65 K to 473.15 K and from 50 % to 70 %. The densities and viscosities were measured in ranges of temperature and absorbent mass fraction from 283.15 K to 413.15 K and from 30 % to 65 %. The specific heat capacities were measured in ranges of temperature and absorbent mass fraction from 303.15 K to 373.15 K and from 30 % to 60 %. Regression equations for solubility, vapor pressure, density, viscosity, and specific heat capacity were obtained by a least-squares method from the experimental data. The average absolute relative deviations of each property between the measured data and the individual calculated value from these regression equations were 0.13 %, 0.14 %, 0.12 %, 0.14 %, and 0.23 %, respectively. This research will be helpful when LiNO3/H2O is utilized as a working fluid for the absorption heat pump.
Compounds
# Formula Name
1 LiNO3 lithium nitrate
2 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • atomic absorption spectrophotometer
  • 10
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 116
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 77
  • POMD
  • 2
  • 1
  • Viscosity, Pa*s ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 76
  • POMD
  • 2
  • 1
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Mass fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Small sample (50 mg) DSC
  • 53
  • POMD
  • 2
  • 1
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • atomic absorption spectrophotometer
  • 4