Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Physical Properties of HCFO-1233zd(E)

Hulse, R. J. J.[Ryan J.], Basu, R. S.[Rajat S], Singh, R. R.[Rajiv R], Thomas, R. H. P.[Raymond H. P.]
J. Chem. Eng. Data 2012, 57, 12, 3581-3586
ABSTRACT
A new low global warming potential (GWP) fluid hydrochlorofluoroolefin trans-isomer of 1-chloro-3,3,3-trifluoro-propene (HCFO-1233zd(E)) has been developed in our laboratory. HCFO-1233zd(E) has a very short atmospheric lifetime of 26 days and a global warming potential (GWP) of less than 5 (Wong et al., http://www.honeywell-solsticelba.com.product-info/environmental-regulatory/atmospheric-impact, 2012). This makes it an excellent environmentally friendly candidate for many applications including refrigeration, foam expansion agents, and as solvents. In this work we have presented our measurements of physical properties like the boiling point, critical temperature, vapor pressure, liquid density, and surface tension of HCFO-1233zd(E). We have also provided our calculated ideal gas heat capacity at constant pressure using quantum mechanical theory. Temperature-dependent properties are correlated with standard forms of equations and described in the paper.
Compounds
# Formula Name
1 C3H2ClF3 (E)-1-chloro-3,3,3-trifluoroprop-1-ene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Critical temperature, K ; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 1
  • POMD
  • 1
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Capillary rise
  • 3
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 16
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Vibrating tube method
  • 13
  • POMD
  • 1
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 6