Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Pressure-density-temperature measurements of binary mixtures rich in CO2 for CCS applications

Mazzoccoli, M.[Michela], Bosio, B.[Barbara], Arato, E.[Elisabetta]
J. Chem. Eng. Data 2012, 57, 10, 2774-2783
ABSTRACT
Often, power plants and industrial production plants large point sources of CO2 are situated at long distances from storage locations; thus the transportation of the resulting CO2-rich streams, containing small amounts of impurities, is required from the point of capture to the storage site, making it very important to understand the thermodynamic properties of CO2-rich mixtures. The range of conditions studied in this work are of great interest for carbon capture and storage applications, in particular for pipeline transportation of CO2-mixtures. Pressure density temperature measurements were taken for binary mixtures of carbon dioxide with nitrogen, oxygen, or argon. Density was measured for all of the binary systems for temperatures between 273.15 K and 293.15 K and pressures between 1 MPa and 20 MPa, using a vibrating tube densimeter, Anton Paar DMA 512-HPM. The molar CO2 concentration was greater than 85 % for all mixtures tested.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 N2 nitrogen
3 O2 oxygen
4 Ar argon
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • Vibrating tube method
  • 15
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 50
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Mole fraction - 1; Gas
  • Gas
  • Vibrating tube method
  • 34
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Vibrating tube method
  • 86
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Fluid (supercritical or subcritical phases)
  • Pressure, kPa; Fluid (supercritical or subcritical phases)
  • Mole fraction - 1; Fluid (supercritical or subcritical phases)
  • Temperature, K; Fluid (supercritical or subcritical phases)
  • Fluid (supercritical or subcritical phases)
  • Vibrating tube method
  • 2
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Mole fraction - 1; Gas
  • Gas
  • Vibrating tube method
  • 35
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Vibrating tube method
  • 72
  • POMD
  • 1
  • 4
  • Mass density, kg/m3 ; Gas
  • Mole fraction - 1; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • Vibrating tube method
  • 33
  • POMD
  • 1
  • 4
  • Mass density, kg/m3 ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 89