Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Densities of Partially Carbonated Aqueous Diethanolamine and Methyldiethanolamine Solutions

Jayarathna, S. A.[Sanoja A.], Kottage, D.[Deshaka], Eimer, D. A.[Dag A.], Melaaen, M. C.[Morten C.]
J. Chem. Eng. Data 2012, 57, 11, 2975-2984
ABSTRACT
Densities of carbon dioxide loaded (partially carbonated), aqueous diethanolamine (DEA) solutions and aqueous methyldiethanolamine (MDEA) solutions are measured within a temperature range from (293.15 to 423.15) K. The series of DEA and MDEA aqueous solutions cover a range of amine mass ratios from (0.5 to 0.8) and a range of CO2 loading from (0 to 0.5) mol CO2*mol amine 1. All of the data points are compared with the predictions of the model from Weiland et al., and data regression is performed to fit selected parameters of the model. Predictions from the model fitted in this work are compared with the data measured in this work. The capability of the fitted model to predict the densities of the partially carbonated aqueous DEA and MDEA solutions with amine mass ratios different from what is used in this work is analyzed.
Compounds
# Formula Name
1 C4H11NO2 diethanolamine
2 CO2 carbon dioxide
3 H2O water
4 C5H13NO2 N-methyldiethanolamine
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 14
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 56
  • POMD
  • 4
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 56
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 326
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 219
  • POMD
  • 4
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Mass fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 218
  • POMD
  • 4
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Mass fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 174