Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubilities of Bis(2,4,6-trimethylbenzoyl)phenylphosphine Oxide in Different Organic Solvents at Several Temperatures

Wang, Z.[Zhongwei], Yu, Q.[Qing], Liu, Y.[Ying], Zhao, J.[Jian], Lu, Z.[Zongling], Sun, J.[Jutao]
J. Chem. Eng. Data 2012, 57, 12, 3340-3343
ABSTRACT
The mole fraction solubilities of bis(2,4,6-trimethylbenzoyl)phenylphosphine oxide (BPPO) in different organic solvents such as methanol, ethanol, ethyl acetate, cyclohexane, 2-propanol, acetonitrile, n-hexane, dichloromethane, dichloroethane, chloroform, benzene, and toluene were measured at a designated temperature of (295 to 345) K by the gravimetrical method. The solubilities of BPPO in dichloromethane, dichloroethane, chloroform, benzene, and toluene were all higher than 25 g*100 g 1 at 295.4 K. The mole fraction solubilities (x) of BPPO in methanol, ethanol, ethyl acetate, cyclohexane, 2-propanol, acetonitrile, and n-hexane were correlated as a function of temperature. Results showed that the calculated solubilities were in good agreement with the experimental solubility data.
Compounds
# Formula Name
1 C26H27O3P (phenylphosphoryl)bis(mesitylmethanone)
2 CH4O methanol
3 C2H6O ethanol
4 C4H8O2 ethyl acetate
5 C6H12 cyclohexane
6 C3H8O propan-2-ol
7 C2H3N acetonitrile
8 C6H14 hexane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetric
  • 8
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetric
  • 8
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetric
  • 10
  • POMD
  • 5
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetric
  • 10
  • POMD
  • 6
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetric
  • 10
  • POMD
  • 7
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Gravimetric
  • 9
  • POMD
  • 8
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • v
  • 8