Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Effect of Temperature and Concentration on Density, Apparent Molar Volume, Ultrasound Velocity, Isoentropic Compressibility, Viscosity, and Conductivity of Hexadecyldimethylethylammonium Bromide

Sheikh, F. A.[Fayaz Ahmad], Bhat, P. A.[Parvaiz Ahmad]
J. Chem. Eng. Data 2012, 57, 12, 3368-3374
ABSTRACT
Physicochemical properties like density, apparent molar volume, ultrasound velocity, isoentropic compressibility, viscosity, and conductivity of aqueous solutions of hexadecyldimethylethylammonoum bromide as a function of concentration at different temperatures ranging from (298.15 to 323.15) K have been determined. Critical micellar concentration values depend upon the technique used. Density data have been used to calculate the apparent molar volume of the surfactant. Viscosity data have been employed to compute degrees of hydration based on the Vand and Einstien equation. Conductivity measurements have been used to evaluate the degree of counterion binding and various thermodynamic paramaters.
Compounds
# Formula Name
1 C20H44BrN ethylhexadecyldimethylammonium bromide
2 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Electrical conductivity, S/m ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Dip type conductivity cell
  • 40
  • POMD
  • 1
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 48
  • POMD
  • 1
  • 2
  • Speed of sound, m/s ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Sing-around technique in a fixed-path interferometer
  • 48
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 48