Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

On the Solubility of Carbon Dioxide in Binary Water Methanol Mixtures

Schuler, N., Hecht, K. T., Kraut, M., Dittmeyer, R.
J. Chem. Eng. Data 2012, 57, 8, 2304-2308
ABSTRACT
The solubility of carbon dioxide in binary mixtures of water and methanol containing up to 12.37 mass % methanol has been measured at temperatures between 298 K and 333 K at atmospheric pressure. The solubility increases with increasing methanol content, but the influence is, at least at low temperatures, much smaller than linear interpolation would suggest. Employing the van't Hoff equation for ideal solutions, a correlation has been proposed that fits the measurements for up to 8.16 mass % methanol in water.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 CH4O methanol
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 3
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • gas volume change
  • 7
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • gas volume change
  • 6
  • POMD
  • 2
  • 1
  • 3
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Solvent: Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • gas volume change
  • 42