Thermodynamics Research Center / ThermoML | Journal of Chemical and Engineering Data

Solubilities of 3-Methoxy-N-phenylaniline and 3-(Methylthio)-N-phenylaniline in Five Organic Solvents (285 K to 333.75 K)

Jia, Y.-x.[Yin-xia], Qian, C.[Chao], Chen, X.-Z.[Xin-Zhi], He, C.-H.[Chao-Hong]
J. Chem. Eng. Data 2012, 57, 5, 1581-1585
ABSTRACT
The solubilities of 3-methoxy-N-phenylaniline and 3-(methylthio)-N-phenylaniline in pure organic solvents of methanol, acetone, ethyl acetate, chloroform, and 1,2-dichloroethane were measured at temperatures ranging from 285 K to 333.75 K using the laser monitoring dynamic method. The experimental data were correlated with the Apelblat equation; the solubilities correlated by the model are in good agreement with experimental values. The mean relative deviations s are less than 1.5 % and the root-mean-square deviations (rmsd) less than 0.10 %.
Compounds
# Formula Name
1 C13H13NO 3-methoxy-N-phenylaniline
2 C13H13NS 3-(methylthio)-N-phenylaniline
3 CH4O methanol
4 C3H6O acetone
5 C4H8O2 ethyl acetate
6 CHCl3 trichloromethane
7 C2H4Cl2 1,2-dichloroethane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Laser Monitering Observation
  • 9
  • POMD
  • 1
  • 5
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Laser Monitering Observation
  • 10
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Laser Monitering Observation
  • 8
  • POMD
  • 1
  • 7
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Laser Monitering Observation
  • 10
  • POMD
  • 6
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Laser Monitering Observation
  • 8
  • POMD
  • 3
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Laser Monitering Observation
  • 9
  • POMD
  • 5
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Laser Monitering Observation
  • 10
  • POMD
  • 4
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Laser Monitering Observation
  • 8
  • POMD
  • 7
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Laser Monitering Observation
  • 11
  • POMD
  • 6
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Laser Monitering Observation
  • 8